A hectare is a hundred-metre square
A hectare is 10,000 m² — a square 100 m on a side, or roughly a rugby pitch. An acre is 4,046.8564224 m², defined through the international foot, which makes a hectare exactly 2.47105381… acres. Farm sizes, forestry, planning applications and most land registries outside the US and UK use hectares; US, UK, Canadian and Australian real estate still quote acres. 100 hectares is a square kilometre; 259 hectares is a square mile.
Rough conversion in your head
Multiply hectares by 2½ for acres: 40 ha → 100 acres (true 98.8). Multiply acres by 0.4 for hectares: 160 acres, a US quarter-section, → 64 ha (true 64.7). Both are within about 1%, which is closer than most field boundaries are surveyed.